Syntheses and31P NMR Studies of Cyclic Oxothiomolybdate(V) Molecular Rings: Exchange Properties and Crystal Structures of the Monophosphate Decamer [(H2PO4)Mo10S10O10(OH)11(H2O)2]2− and the Diphosphate Dodecamer [(HPO4)2Mo12S12O12(OH)12(H2O)2]4−
1999; Wiley; Volume: 5; Issue: 11 Linguagem: Inglês
10.1002/(sici)1521-3765(19991105)5
ISSN1521-3765
AutoresEmmanuel Cadot, Bernadette Salignac, Thierry Loiseau, Anne Dolbecq, F. Sécheresse,
Tópico(s)Nanocluster Synthesis and Applications
ResumoChemistry – A European JournalVolume 5, Issue 11 p. 3390-3398 Full Paper Syntheses and 31P NMR Studies of Cyclic Oxothiomolybdate(V) Molecular Rings: Exchange Properties and Crystal Structures of the Monophosphate Decamer [(H2PO4)Mo10S10O10(OH)11(H2O)2]2− and the Diphosphate Dodecamer [(HPO4)2Mo12S12O12(OH)12(H2O)2]4− Emmanuel Cadot, Emmanuel Cadot Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorBernadette Salignac, Bernadette Salignac Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorThierry Loiseau, Thierry Loiseau Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorAnne Dolbecq, Anne Dolbecq Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorFrancis Sécheresse, Francis Sécheresse secheres@chimie.uvsq.fr Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this author Emmanuel Cadot, Emmanuel Cadot Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorBernadette Salignac, Bernadette Salignac Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorThierry Loiseau, Thierry Loiseau Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorAnne Dolbecq, Anne Dolbecq Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this authorFrancis Sécheresse, Francis Sécheresse secheres@chimie.uvsq.fr Institut Lavoisier. IREM, UMR C 0173, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, F-78035 Versailles (France)Search for more papers by this author First published: 29 October 1999 https://doi.org/10.1002/(SICI)1521-3765(19991105)5:11 3.0.CO;2-BCitations: 34AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Two oxothiophosphato anions are obtained from solutions containing the [Mo2S2O2]2+ precursor and phosphate ions. The monophosphato anion reveals a Mo10 decameric structure and the diphosphato anion, a Mo12 dodecameric one. Both compounds exhibit an open cavity containing the phosphate ions. A 31P NMR study in solution (see picture) shows that the two compounds are involved in the same equilibrium and that the inner phosphate groups are labile enough to be exchanged. Citing Literature Volume5, Issue115 November 1999Pages 3390-3398 RelatedInformation
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