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Syntheses and characterization of the oxidized phthalocyanine compounds [Ni(pc)]3[ReO4]2·C10H7Cl, [Cu(pc)]3[SbF6]2·C10H7Cl, [Cu(pc)]3[AsF6]2·C10H7Cl, [H2(pc)]3[SbF6]2·C10H7Cl, [Ni(pc)]3[SbF6]2·C10H7Cl, and [H2(pc)]3[AsF6]2·C10H7Cl

2002; Elsevier BV; Volume: 328; Issue: 1 Linguagem: Inglês

10.1016/s0020-1693(01)00730-7

1873-3255

A.S. Gardberg, A.E. Sprauve, James A. Ibers,

Inorganic Fluorides and Related Compounds

A series of partially-oxidized phthalocyanine (pc) compounds ([Ni(pc)]3[ReO4]2·C10H7Cl, [Cu(pc)]3[SbF6]2·C10H7Cl, [Cu(pc)]3[AsF6]2·C10H7Cl, [H2(pc)]3[SbF6]2·C10H7Cl, and [Ni(pc)]3[SbF6]2·C10H7Cl) were synthesized galvanostatically. Their structures were determined by means of conventional crystallographic methods. An improved structure of [H2(pc)]3[AsF6]2·C10H7Cl was determined from synchrotron data. The isostructural extended structures of these compounds comprise stacked trimers of M(pc) rings with anions and disordered solvents in parallel channels. Conductivity data for [Cu(pc)]3[SbF6]2·C10H7Cl indicate that it is a semiconductor (EA=0.22 eV).