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Artigo Revisado por pares
BIBTEX RIS

Promotion of acetophenone formation from methyl(phenyl)rhodium carbonyl complexes by organic halides

1987; Elsevier BV; Volume: 330; Issue: 3 Linguagem: Inglês

10.1016/s0022-328x(00)99062-4

ISSN

1872-8561

Autores

Glenn J. Sunley, Francesco Paolo Fanizzi, Isabel M. Sáez, Peter M. Maitlis,

Tópico(s)

Catalytic Cross-Coupling Reactions

Resumo

[C5Me5RhPh(CO)CH3] reacted thermally to give acetophenone (27%) and toluene (9%); acetophenone formation was substantially increased in the presence of halobenzenes PhX (the order of effectiveness being X = I > Br > Cl) or methyl iodide, but 1-electron oxidisers promoted CC coupling (toluene formation).

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