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Synthesis and Structure of a Hexaazadiphosphadiarsatricyclodecane

1976; Wiley; Volume: 15; Issue: 11 Linguagem: Inglês

10.1002/anie.197607011

1521-3773

Otto J. Scherer, Walter Gläßel, Gottfried Hüttner, Albin Frank, Péter Friedrich,

Asymmetric Hydrogenation and Catalysis

Angewandte Chemie International Edition in EnglishVolume 15, Issue 11 p. 701-702 Communication Synthesis and Structure of a Hexaazadiphosphadiarsatricyclodecane Prof. Dr. Otto J. Scherer, Prof. Dr. Otto J. Scherer Fachbereich Chemie der Universität, Postfach 3049, D-6750 Kaiserslautern (Germany)Search for more papers by this authorDipl.-Chem. Walter Glässel, Dipl.-Chem. Walter Glässel Fachbereich Chemie der Universität, Postfach 3049, D-6750 Kaiserslautern (Germany)Search for more papers by this authorDoz. Dr. Gottfried Huttner, Doz. Dr. Gottfried Huttner Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Search for more papers by this authorDipl.-Chem. Albin Frank, Dipl.-Chem. Albin Frank Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Search for more papers by this authorDipl.-Chem. Peter Friedrich, Corresponding Author Dipl.-Chem. Peter Friedrich Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Search for more papers by this author Prof. Dr. Otto J. Scherer, Prof. Dr. Otto J. Scherer Fachbereich Chemie der Universität, Postfach 3049, D-6750 Kaiserslautern (Germany)Search for more papers by this authorDipl.-Chem. Walter Glässel, Dipl.-Chem. Walter Glässel Fachbereich Chemie der Universität, Postfach 3049, D-6750 Kaiserslautern (Germany)Search for more papers by this authorDoz. Dr. Gottfried Huttner, Doz. Dr. Gottfried Huttner Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Search for more papers by this authorDipl.-Chem. Albin Frank, Dipl.-Chem. Albin Frank Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Search for more papers by this authorDipl.-Chem. Peter Friedrich, Corresponding Author Dipl.-Chem. Peter Friedrich Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)Search for more papers by this author First published: November 1976 https://doi.org/10.1002/anie.197607011Citations: 17AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat No abstract is available for this article. References 1 For the preparation cf. O. J. Scherer and W. Glässel, Angew. Chem. 87, 667 (1975); Angew. Chem. Int. Ed. Engl. 14, 629 (1975). 2 31 PNMR (20% solution in CHCl3, 85% H3PO4 ext.): δ = −158.2ppm. 1HNMR (10% solution in C6H6, TMS int.): δCH3C = −1.48(s), δCH3N = −2.68 ppm (d), 3JPH = 16.2 Hz. 3 The phosphorus in (2) is obviously shielded in such a way that—in contrast to the violent oxidation that already takes place at room temperature in the case of most tris(amino)phosphanes—no reaction occurs even with warm CCl4. 4 Diffractometer SYNTEX-P 21, graphite monochromator, MoKα, λ = 71.069 pm.—C10H24As2Cl2N6P2 (2), monoclinic, space group P21/c, a = 942 (1), b = 703 (1), c = 1631 (1) pm, β = 113.47°, Z = 2.737 independent diffraction intensities (I ≥ 3.1 σ) in the range 3≤ 2θ ≤ 40°, solution conventional, R1, = 0.051. Structure resolving apparatus SYNTEX-XTL.—Parameters (atom/x:a/y:b/z:c): As / 0.1470(1) / 0.2149(2) / 0.0310(1)—P / 0.1331(4) / 0.6164(4) / −0.0271(2)—CI / 0.3782(4) / 0.1713(5) / 0.1438(2)—N(1) / 0.202(1) / 0.396(1) / −0.0338(6)—N(2) / 0.1313(9) / 0.591(1)/0.0766(5)—N(3)/0.070(1)/0.406(1)/0.0SS2(5)—C(1)/0.242(1)/0.332(2)/ −0.1117(7)—C(11) / 0.088(2) /0.269(3)/ −0.1896(9)—C(12) / 0.354(2)/ 0.172(2) / −0.0811(9)—C(13)/0.308(2)/0.500(3)/ −0.1421(9)—C(2) / 0.272(1) / 0.645(2) / 0.1559(8). 5 J. Weiss and W. Eisenhuth, Z. Naturforsch. 22b, 454 (1967); R. Ullmann and H. Nöth, Chem. Ber. 109, 2581 (1976); literature cited therein. Citing Literature Volume15, Issue11November 1976Pages 701-702 ReferencesRelatedInformation