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N-Confused Porphyrin-Bearing m eso -Perfluorophenyl Groups: A Potential Agent That Forms Stable Square-Planar Complexes with Cu(II) and Ag(III)

2003; American Chemical Society; Volume: 5; Issue: 8 Linguagem: Inglês

10.1021/ol034227l

1523-7060

Hiromitsu Maeda, Atsuhiro Osuka, Yuichi Ishikawa, I. Aritome, Yoshio Hisaeda, Hiroyuki Furuta,

Luminescence and Fluorescent Materials

[reaction: see text] N-Confused porphyrin (NCP) bearing pentafluorophenyl groups at meso-positions, which were obtained from N-confused dipyrromethane in ca. 20% yield, can form Cu(II) complex as well as Ag(III), Ni(II), and Pd(II) complexes. The square-planar structures of all these metal complexes were elucidated by X-ray single-crystal analyses.