Complimentary Polytopic Interactions
2000; Wiley; Volume: 39; Issue: 13 Linguagem: Inglês
10.1002/1521-3773(20000703)39
ISSN1521-3773
AutoresEkaterina O. Arikainen, N. Boden, Richard J. Bushby, Owen R. Lozman, Jeremy G. Vinter, Andrew Wood,
Tópico(s)Organic Electronics and Photovoltaics
ResumoThe remarkable phase behavior for binary mixtures of large-core polynuclear aromatic species and small-core discogens cannot be explained simply in terms of net quadrupolar or charge-transfer interactions. The stable π stacking in these mixtures can instead be rationalized by invoking a complimentary polytopic interaction. The picture shows the stacking (in elevation and plan views) between such species.
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