Artigo Revisado por pares

Complimentary Polytopic Interactions

2000; Wiley; Volume: 39; Issue: 13 Linguagem: Inglês

10.1002/1521-3773(20000703)39

ISSN

1521-3773

Autores

Ekaterina O. Arikainen, N. Boden, Richard J. Bushby, Owen R. Lozman, Jeremy G. Vinter, Andrew Wood,

Tópico(s)

Organic Electronics and Photovoltaics

Resumo

The remarkable phase behavior for binary mixtures of large-core polynuclear aromatic species and small-core discogens cannot be explained simply in terms of net quadrupolar or charge-transfer interactions. The stable π stacking in these mixtures can instead be rationalized by invoking a complimentary polytopic interaction. The picture shows the stacking (in elevation and plan views) between such species.

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