Thermischer zerfall von β-phenyl- und β,β-diphenyl- nitroalkanen
1988; Elsevier BV; Volume: 29; Issue: 23 Linguagem: Inglês
10.1016/0040-4039(88)85215-8
ISSN1873-3581
AutoresKatharina Fritzsche, Hans‐Dieter Beckhaus, Christoph Rüchardt,
Tópico(s)Inorganic and Organometallic Chemistry
ResumoElimination of nitrous acid is the exclusive reaction path for the thermal decomposition of the nitroalkanes 1, 2 and 5. Homolytic CC-cleavage cannot compete. A concerted β-elimination is the favoured mechanism.
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