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Artigo Revisado por pares
BIBTEX RIS

Enzymatic resolution of planar chiral ferrocene derivatives

1992; Wiley; Volume: 55; Issue: 4 Linguagem: Inglês

10.1002/jctb.280550404

ISSN

1097-4660

Autores

Taeko Izumi, Toshimi Hino,

Tópico(s)

Molecular Junctions and Nanostructures

Resumo

Abstract Racemic 3‐methyl, 2‐ethyl, 2‐bromo, and 2‐trimethylsilyl derivatives of formylferrocene were kinetically resolved by enantioselective reduction with a fermenting baker's yeast. Moreover, 2‐methyl, 3‐methyl, 2‐ethyl, 2‐bromo, and 2‐trimethylsilyl derivatives of hydroxymethylferrocene were optically resolved with lipases by transesterification using vinyl esters.

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