Palladium-catalyzed allylation of lithium 3-alkenyl-1-cyclopentenolates-triethylborane and its application to a selective synthesis of methyl (z)-jasmonate1
1985; Elsevier BV; Volume: 26; Issue: 18 Linguagem: Inglês
10.1016/s0040-4039(00)98955-x
ISSN1873-3581
AutoresFen‐Tair Luo, Ei‐ichi Negishi,
Tópico(s)Traditional and Medicinal Uses of Annonaceae
ResumoA Pd-catalyzed allylation of 3-substituted 1-cyclopentenolates with readily obtainable and storable γ-monosubstituted (Z)-allylic acetates in a 1:1 ratio in the presence of 2 mol % of Pd(PPh3)4 featuring high yields and high stereo- and regioselectivities has been developed and applied to the synthesis of methyl (Z)-jasmonate.
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