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Vinyl ester and unsaturated polyester resins in contact with different chemicals: Dynamic mechanical behavior

1999; Wiley; Volume: 71; Issue: 1 Linguagem: Inglês

10.1002/(sici)1097-4628(19990103)71

1097-4628

A. Valea, María Luz Cacheiro González, Iñaki Mondragòn,

Epoxy Resin Curing Processes

Journal of Applied Polymer ScienceVolume 71, Issue 1 p. 21-28 Research Article Vinyl ester and unsaturated polyester resins in contact with different chemicals: Dynamic mechanical behavior A. Valea, Corresponding Author A. Valea Departamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, SpainDepartamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, Spain===Search for more papers by this authorM. L. Gonzalez, M. L. Gonzalez Departamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, SpainSearch for more papers by this authorI. Mondragon, I. Mondragon Departamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, SpainSearch for more papers by this author A. Valea, Corresponding Author A. Valea Departamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, SpainDepartamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, Spain===Search for more papers by this authorM. L. Gonzalez, M. L. Gonzalez Departamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, SpainSearch for more papers by this authorI. Mondragon, I. Mondragon Departamento Ingeniería Química y del Medio Ambiente, Escuela Universitaria Ingeniería Técnica Industrial, Universidad País Vasco/Euskal Herriko Unibertsitatea, Avda. Felipe IV, 1 B, 20011 San Sebastián/Donostia, SpainSearch for more papers by this author First published: 03 January 1999 https://doi.org/10.1002/(SICI)1097-4628(19990103)71:1 3.0.CO;2-YCitations: 22Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Abstract A prior study has shown for a vinyl ester resin that the adequate choice of the curing conditions becomes completely necessary to reach the maximum glass transition temperature. In the same study, the variations produced in the dynamic mechanical properties because of exposure to different solvents were related to the chemical structure of both the resin and solvent. This investigation was undertaken in an attempt to analyze the effects of solvent exposure on the viscoelastic properties of resins currently used for applications in which the resin is kept in contact with the solvents. Several vinyl ester resins as well as various unsaturated polyester resins immersed in different liquids were investigated. The influence of exposure time to the solvent as well as that for the temperature were characterized using dynamic mechanical analysis. The chemical structure of the resin was found to be determinant in the changes produced after solvent exposure. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 21–28, 1999 REFERENCES 1 Launikitis M. B. in Handbook of Composites Vol. 3, G. Lubin Ed., Van Nostrand Reinhold, New York, 1982, pp. 38– 49. 2 Ghorbel I.; Valentin D. Polym. Compos. 1994, 14, 324. 3 Verdu J.; in Paris Vieillissement des Plastiques, Afnor Techniques, 1984. 4 Springer G. S.; Sanders B. A.; Tung R. W.; Environmental Effects on Composite Materials Vols. 1 and 2, Technomic, Westport, CT, 1981. 5 Mijovic J. Polym. Compos. 1983, 4, 73. 6 Benameur T.; Granger R.; Vergnaud J. M. Polym. Test, 1995, 14, 35. 7 Valea A.; Martinez I.; Gonzalez M.L.; Eceiza A.; Mondragon I. J. Appl. Polym. Sci. to appear it is the other paper that I am sending you. 8 Yang Y. S.; Lee L. J. Polymer 1988, 29, 1793. 9 Jacobs P. M.; Jones F. R. Polymer 1992, 33, 1418. 10 Huang Y. J.; Chen C. J. J. Appl. Polym. Sci. 1992, 46, 1573. 11 de la Caba K.; Guerrero P.; Eceiza A.; Mondragon I. Eur. Polym. J. 1997, 33, 19. Citing Literature Volume71, Issue13 January 1999Pages 21-28 ReferencesRelatedInformation