Transition metal activation of π-complexed benzene: double nucleophilic additions
1981; Elsevier BV; Volume: 216; Issue: 1 Linguagem: Inglês
10.1016/s0022-328x(00)84005-x
ISSN1872-8561
AutoresLai Yee-Hing, Wilson Tam, K. Peter, C. Vollhardt,
Tópico(s)Catalytic Alkyne Reactions
ResumoTreatment of the η5-cyclopentadienyl-η6-benzenecobalt dication with sodium methoxide in methanol or sodium cyclopentadienide in tetrahydrofuran gives double, vicinal, and stereospecific (exo) addition to the benzene ring in accord with the Davies-Green-Mingos rules.
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