A Dilatometric Study of Compatible Polymer Mixtures
1972; Oxford University Press; Volume: 45; Issue: 5 Linguagem: Inglês
10.1246/bcsj.45.1381
ISSN1348-0634
Autores Tópico(s)Polymer crystallization and properties
ResumoPolymer mixtures of poly(vinyl nitrate) (PVONO2), and poly(vinyl acetate) (PVOAc), which had previously been concluded to be compatible with each other, were investigated by the dilatometric method. As a result, a characteristic behavior of the mixtures was observed. Each mixture showed a single glass-transition temperature (Tg) over the whole range of composition; this temperature was higher than those of pure polymers in the middle region of composition. The transition temperatures of the mixtures obeyed a modified Gordon-Taylor expression. The thermal expansion coefficients of the mixtures are discussed in relation to the effect of blending.
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