A Conjugated Polycarbazole Ring around a Porphyrin
2006; Wiley; Volume: 45; Issue: 28 Linguagem: Inglês
10.1002/anie.200601131
ISSN1521-3773
AutoresSung‐Hyun Jung, Wojciech Pisula, Ali Rouhanipour, Hans Joachim Räder, Josemon Jacob, Kläus Müllen,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoRound up: A fully conjugated cyclododeca-2,7-carbazole is prepared around a porphyrin template and the corresponding empty macrocycle then released. Single molecules could be visualized by STM (see image) and their arrangement by atomic force microscopy. The macrocycles self-assemble into a hexagonal array of columns. Efficient energy transfer occurs from the peripheral carbazole π system to the central porphyrin core. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z601131_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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