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MOF-5/n-Bu4NBr: an efficient catalyst system for the synthesis of cyclic carbonates from epoxides and CO2 under mild conditions

2009; Royal Society of Chemistry; Volume: 11; Issue: 7 Linguagem: Inglês

10.1039/b902550b

1463-9270

Jinliang Song, Zhaofu Zhang, Suqin Hu, Tianbin Wu, Tao Jiang, Buxing Han,

Chemical Synthesis and Reactions

The development of efficient heterogeneous catalysts for the cycloaddition of CO2 with epoxides to produce five-membered cyclic carbonates under mild reaction conditions is of great importance. In this work, the coupling reaction of CO2 with propylene oxide (PO) to produce propylene carbonate (PC) catalyzed by MOF-5 (metal-organic frameworks) in the presence of quaternary ammonium salts (Me4NCl, Me4NBr, Et4NBr, n-Pr4NBr, n-Bu4NBr) was studied in different conditions. It was discovered that MOF-5 and quaternary ammonium salts had excellent synergetic effect in promoting the reaction, and the MOF-5/n-Bu4NBr catalytic system was the most efficient among them. The optimal temperature for the reaction was around 50 °C. The reaction could be completed in 6 h at low CO2 pressure with very high selectivity. A decrease of the yield of PC was not noticeable after MOF-5 was reused three times, indicating that the MOF-5 was stable. The MOF-5/n-Bu4NBr catalytic system was also very active and selective for the cycloaddition of CO2 with other epoxides, such as glycidyl phenyl ether, epichlorohydrin and styrene oxide. The mechanism for the coupling reaction is also discussed.