Adsorption and electrocatalytic dechlorination of pentachlorophenol on palladium-loaded activated carbon fibers
2005; Elsevier BV; Volume: 47; Issue: 1-2 Linguagem: Inglês
10.1016/j.seppur.2005.06.005
ISSN1873-3794
AutoresChunyue Cui, Xie Quan, Shuo Chen, Huimin Zhao,
Tópico(s)Adsorption and biosorption for pollutant removal
ResumoThe palladium-loaded activated carbon fiber (Pd/ACF) adsorption/electroreduction process was employed for electrocatalytic dechlorination of pentachlorophenol (PCP) solution. PCP in water was adsorbed onto Pd (4.2 wt.%)/ACF first and then the PCP was degraded at a constant current. At 25 mA/cm2, the degradation of PCP was 94.8% after electrolysis of 200 min and phenol was the main product with a yield of 86.1% and a current efficiency of 17.4%. After being reused three times, the Pd (4.2 wt.%)/ACF cathode still had acceptable electrocatalytic activity.
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