Portal de Periódicos da CAPES

Thermal and structural analysis of heparin–PEO–PDMS–PEO–heparin pentablock copolymers

1994; Wiley; Volume: 54; Issue: 12 Linguagem: Inglês

10.1002/app.1994.070541209

1097-4628

Yong–Joo Kim, Yong Kiel Sung, Ai Zhi Piao, David W. Grainger, Teruo Okano, Sung Wan Kim,

Polymer composites and self-healing

Abstract ABCBA‐type amphiphilic block copolymers comprising polydimethylsiloxane (PDMS), poly(ethylene oxide) (PEO), and heparin segments were synthesized by coupling reactions between end‐functionalized oligomers. These multiblock copolymers were characterized to examine bulk properties using 1 H‐NMR, FTIR, end‐group analysis, and sulfur elemental analysis. Block copolymers were further characterized in bulk using differential scanning calorimetry and X‐ray diffraction measurements. The PDMS glass transition remains unchanged with increasing PEO content, indicating coexistence of pure PDMS with mixed phases. Furthermore, endothermic melting of the block copolymers shifts to higher temperatures and becomes more intense with increasing PEO molecular weight. Additionally, the crystallinity of the PEO segment in the block copolymers increases with increasing PEO molecular weight. The PEO melting endotherm peak shifts from near 318 to 323 K with annealing. In the cooling thermogram, the block copolymers exhibit two crystallization exotherms, one near 303 K and the other near 193 K, attributed to PEO and PDMS recrystallization and nucleation, respectively. © 1994 John Wiley & Sons, Inc.