Wacker Oxidation of 1‐Decene to 2‐Decanone in the Presence of a Chemically Modified Cyclodextrin System: A Happy Union of Host–Guest Chemistry and Homogeneous Catalysis
1994; Wiley; Volume: 33; Issue: 20 Linguagem: Inglês
10.1002/anie.199421001
ISSN1521-3773
AutoresÉric Monflier, Emilie Blouet, Y. Barbaux, André Mortreux,
Tópico(s)Oxidative Organic Chemistry Reactions
ResumoOnly assisted by molecular recognition and phase transfer is the title reaction efficient. The stability of the complexes of various host cyclodextrins with decene and decanone is mainly determined by the size of the cyclodextrin aperture; the solubility of the cyclodextrins and their complexes in the aqueous and organic phases depends on the chemical modification of the cyclodextrin. With β-cyclodextrin 1 and PdSO4/H9PV6Mo6O40/CuSO4 as the catalytic system, 1-decene is oxidized with O2 to give 2-decanone in 98% yield.
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