Hydroxy group-assisted isomerization and alkylation of allylsilanes in basic media. α-(1-trimethylsilyallyl) ketone as an α-alkenyl ketone equivalent.

Artigo Revisado por pares

Hydroxy group-assisted isomerization and alkylation of allylsilanes in basic media. α-(1-trimethylsilyallyl) ketone as an α-alkenyl ketone equivalent.

1983; Elsevier BV; Volume: 24; Issue: 39 Linguagem: Inglês

10.1016/s0040-4039(00)88311-2

ISSN

1873-3581

Autores

Hirokazu Urabe, Isao Kuwajima,

Tópico(s)

Chemical Synthesis and Reactions

Resumo

Regioselective protonation and alkylation of a certain hydroxyallylsilane have been effected in basic media. An application of these reactions to a facile preparation of 3-hydroxy-1,5-hexadiene systems has also been achieved.

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Hydroxy group-assisted isomerization and alkylation of allylsilanes in basic media. α-(1-trimethylsilyallyl) ketone as an α-alkenyl ketone equivalent.