Highly Diastereoselective Nucleophilic Addition to Myrtenal. Straightforward Synthesis of an Enantiopure Scorpionate Ligand
2007; American Chemical Society; Volume: 46; Issue: 21 Linguagem: Inglês
10.1021/ic701388w
ISSN1520-510X
AutoresAntonío Otero, Juan Fernández‐Baeza, Antonío Antiñolo, Juan Tejeda, Agustín Lara‐Sánchez, Luis F. Sánchez‐Barba, Margarita Sánchez‐Molina, Sonia Franco, I. López-Solera, Ana M. Rodrı́guez,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoThe work described here represents the first example in which an efficient and highly diastereoselective nucleophilic 1,2-addition of an organolithium reagent has been performed on a carbonylic prostereogenic center to give an enantiopure scorpionate ligand in only one step.
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