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Normal Coordinate Analysis of PF5, PF2Cl3, and PCl5

1965; American Institute of Physics; Volume: 43; Issue: 10 Linguagem: Inglês

10.1063/1.1696500

1520-9032

Peter C. Van Der Voorn, Keith F. Purcell, Russell S. Drago,

Inorganic and Organometallic Chemistry

Normal coordinate analyses have been performed for the series of phosphorus (V) halides—PF5, PF2Cl3, PCl5. The effect of including interaction force constants has been studied in detail. The bond-stretching force constants have been interpreted in connection with molecular orbital calculations for these molecules.