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Reduction of 2,3-Dihydroisoxazoles to β-Amino Ketones and β-Amino Alcohols

2005; American Chemical Society; Volume: 7; Issue: 25 Linguagem: Inglês

10.1021/ol052540c

1523-7060

Patrick Aschwanden, Lisbet Kværnø, R.W. Geisser, Florian Kleinbeck, Erick M. Carreira,

Synthesis and Catalytic Reactions

[chemical reaction: see text]. We report the reduction of 2,3-dihydroisoxazoles to beta-amino ketones and beta-amino alcohols. The latter are obtained in high diastereoselectivity with preference for the syn isomer.