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A Hexaimidazole Ligand Binding Six Octahedral Metal Ions To Give an Infinite 3D α‐Po‐Like Network Through Which Two Independent 2D Hydrogen‐Bonded Networks Interweave

1997; Wiley; Volume: 36; Issue: 24 Linguagem: Inglês

10.1002/anie.199727521

1521-3773

Bernard F. Hoskins, Richard Robson, D.A. Slizys,

Zeolite Catalysis and Synthesis

Angewandte Chemie International Edition in EnglishVolume 36, Issue 24 p. 2752-2755 Communication A Hexaimidazole Ligand Binding Six Octahedral Metal Ions To Give an Infinite 3D α-Po-Like Network Through Which Two Independent 2D Hydrogen-Bonded Networks Interweave† Dr. Bernard F. Hoskins, Dr. Bernard F. Hoskins School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347-5180, e-mail: [email protected]Search for more papers by this authorDr. Richard Robson, Corresponding Author Dr. Richard Robson School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347-5180, e-mail: [email protected]School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347–5180, e-mail: [email protected]Search for more papers by this authorDamian A. Slizys, Damian A. Slizys School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347-5180, e-mail: [email protected]Search for more papers by this author Dr. Bernard F. Hoskins, Dr. Bernard F. Hoskins School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347-5180, e-mail: [email protected]Search for more papers by this authorDr. Richard Robson, Corresponding Author Dr. Richard Robson School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347-5180, e-mail: [email protected]School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347–5180, e-mail: [email protected]Search for more papers by this authorDamian A. Slizys, Damian A. Slizys School of Chemistry, University of Melbourne, Parkville, Victoria 3052 (Australia), Fax: Int. code + (9)347-5180, e-mail: [email protected]Search for more papers by this author First published: January 7, 1997 https://doi.org/10.1002/anie.199727521Citations: 73 † The authors gratefully acknowledge support from the Australian Research Council and the American Chemical Society Petroleum Research Fund. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract The new ligand hexakis(imidazol-1-ylmethyl)benzene (hkimb, 1) forms a heavily hydrated coordination polymer with CdF2 of composition Cd(hkimb)F2 · 14 H2O. A unique aspect of the structure is that the water assembles itself into two independent and different hydrogen-bonded 2D networks, which interweave throughout the 3D α-Po-related coordination polymer network. References 1 D. D. MacNicol, G. A. Downing, Comprehensive Supramolecular Chemistry, Vol. 6, Pergamon, Oxford, 1996, Chap. 14, p. 421. 2 A. S. Jessiman, D. D. MacNicol, P. R. Mallinson, I. Vallance, J. Chem. Soc. Chem. Commun. 1990, 1619. 3 S. R. Batten, B. F. Hoskins, R. Robson, J. Am. Chem. Soc. 1995, 117, 5385. 4 B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins, R. Robson, Chem. Commun. 1996, 1313. 5 B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins, R. Robson, Angew. Chem. 1996, 108, 1795; Angew. Chem. Int. Ed. Engl. 1996, 35, 1691. 6 C. M. Hartshorn, P. J. Steel, Aust. J. Chem. 1995, 48, 1587. 7 C. L. Bowes, G. A. Ozin, Adv. Mater. 1996, 8, 13. 8 G. M. Sheldrick, SHELX-76, Program for crystal structure determination. University of Cambridge, UK, 1976. 9 G. M. Sheldrick, SHELXS-86, Program for crystal structure determination, University of Cambridge in Crystallographic Computing 3 (Eds.: G. M. Sheldrick, C. Kruger, R. Goddard), Oxford University Press, Oxford. 1985, p. 175. 10 G. M. Sheldrick, SHELXL-93; Program for crystal structure refinement, University of Göttingen, 1993. Citing Literature Volume36, Issue24January 7, 1997Pages 2752-2755 ReferencesRelatedInformation