Nucleophilic substitution at sulfinyl sulfur. Factors affecting the inversion to retention ratio in acid-catalyzed alcoholysis of chiral n,n-di isopropyl -toluenesulfinamide
1985; Elsevier BV; Volume: 26; Issue: 46 Linguagem: Inglês
10.1016/s0040-4039(01)80924-2
ISSN1873-3581
AutoresM. Mikotajczyk, I. Drabowicz, Bogdan Bujnicki,
Tópico(s)DNA and Nucleic Acid Chemistry
ResumoThe reaction of chiral N,N-di isopropyl p-toluenesulfinamide with some alcohols catalyzed by trifluoroacetic acid has been found to occur with predominant retention of configuration. The stereochemistry of this reaction is strongly affected by silver perchlorate.
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