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The nature and photochemistry of 2,2-dimethyloxirane radical cations in freonic matrices at 77K

2011; Elsevier BV; Volume: 21; Issue: 3 Linguagem: Inglês

10.1016/j.mencom.2011.04.015

1364-551X

Ivan D. Sorokin, Vladimir I. Feldman, O. L. Mel’nikova, V. I. Pergushov, Daniil A. Tyurin, Mikhail Ya. Melnikov,

Radical Photochemical Reactions

The X-ray irradiation of 2,2-dimethyloxirane in freonic matrices at 77 K results in the trapping of a cyclic radical cation form, presumably, complexed with a matrix molecule, which transforms into a C-centered distonic radical cation under the action of light.