Syntheses and electrochemical behaviour of novel dmit or dmio (dithiolato) cobalt(iii) complexes with a η 5 ‐cyclopentadienyl or η 5 ‐pentamethylcyclopentadienyl ring
1991; Wiley; Volume: 5; Issue: 4 Linguagem: Inglês
10.1002/aoc.590050404
ISSN1099-0739
AutoresHirobumi Ushijima, Susumu Sudoh, Masatsugu Kajitani, Kunio Shimizu, Takeo Akiyama, Akira Sugimori,
Tópico(s)Metal-Organic Frameworks: Synthesis and Applications
ResumoAbstract Four novel cobalt(III) complexes with a cyclopentadienyl or pentamethylcyclopentadienyl ring and dmit or dmio ligands were synthesized, and their electrochemical behaviour was investigated. All these complexes exhibited three one‐electron transfer steps: one reduction and two oxidation steps. In addition, a novel organosulphur compound was afforded by electrochemical oxidation of dmit cobalt complex. Thus, these complexes may have considerable synthetic potential as precursors for electron reservoirs and organosulphur compounds.
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