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Biodiesel production in a counter-current reactive extraction column: Modelling, parametric identification and optimisation

2013; Elsevier BV; Volume: 228; Linguagem: Inglês

10.1016/j.cej.2013.05.040

1873-3212

J.G. Cadavid, Rubén Darío Godoy-Silva, Paulo César Narváez Rincón, Maurício Camargo, C. Fonteix,

Catalysis and Hydrodesulfurization Studies

Reactive extraction is a potential alternative for biodiesel production, in which reaction and glycerol separation are simultaneous, increasing conversion, yield and process productivity. This paper presents a stepwise reaction–separation model for a counter-current reactive extraction column, used in homogeneous-base-catalyzed palm oil methanolysis, and the models' parameters are identified from the results of a set of experimental tests. In addition, multi-criteria optimisation of the process conditions was performed using an evolutionary algorithm. The optimum conditions provide for palm oil conversion of 97.7%, a yield to FAME of 99.5% and a process productivity of 1.4 m3 FAME h−1 m−3 in a single reaction step. Finally, a comparison of the process productivity with co-current and batch processes was made. As the counter-current reactive extraction process does not require the intermediate separation stages required in co-current and batch processes, its productivity is 1.5 and 6.9 times higher than those processes, respectively.