
Europium and terbium carboxylate interactions in monolayers and Langmuir–Blodgett films
1998; Elsevier BV; Volume: 324; Issue: 1-2 Linguagem: Inglês
10.1016/s0040-6090(97)01200-5
ISSN1879-2731
AutoresRodrigo F. Silva, Maria Elisabete Darbello Zaniquelli, Osvaldo Antônio Serra, Í. Torriani, Sandra G. Castro,
Tópico(s)Lipid Membrane Structure and Behavior
ResumoAbstract The interaction of trivalent europium and terbium ions with arachidic acid monolayers is reported. The ions are incorporated into the monolayer from the subphase solution, increasing the minimum area per molecule and modifying the pressure–area isotherms. Europium and terbium arachidate bonding in multilayer films transferred to solid supports is evidenced by FTIR and photophysical measurements. The luminescent films are `Y' type structures, as shown by the X-ray diffraction patterns.
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