Beiträge zur Chemie des Bors, 185 Reaktionen von Metallcarben‐Komplexen mit ( tert ‐Butylimino)‐ (2,2,6,6‐tetramethylpiperidino)boran
1987; Wiley; Volume: 120; Issue: 5 Linguagem: Inglês
10.1002/cber.19871200530
ISSN0009-2940
AutoresHeinrich Nöth, Ulrich Wietelmann,
Tópico(s)Boron Compounds in Chemistry
Resumo[2 + 2] Cycloaddition of the aminoiminoborane 1 with Cp 2 ‐TiCH 2 yields a blue 1‐aza‐2‐bora‐4‐titanacyclobutane derivative 2 . In contrast, Fischer carbenes (CO) 5 M = C(OMe)Me (MCr, W) react in a complex way to produce 1 · M(CO) 5 ( 4 ), tmpB(NHCMe 3 )OMe ( 5 ), and the borylated acetylene derivative 6 .
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