A tactically novel alternative to acyclic stereoselection based on the concept of a replicating chiron — access to 1,3-polyols
1985; Elsevier BV; Volume: 26; Issue: 46 Linguagem: Inglês
10.1016/s0040-4039(01)80905-9
ISSN1873-3581
AutoresStephen Hanessian, Soumya P. Sahoo, Peter Murray,
Tópico(s)Carbohydrate Chemistry and Synthesis
Resumo(S)-Glutamic acid is used as a chiral template to construct seven carbon subunits containing alternating hydroxyl groups with stereochemical control. Enantiomeric and/or diastereomeric 3,5-dideoxy-heptitols are thus obtained.
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