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Palladium(0) catalyzed 3-aza-cope rearrangement of N-allylenamines

1985; Elsevier BV; Volume: 26; Issue: 45 Linguagem: Inglês

10.1016/s0040-4039(01)80888-1

1873-3581

Shun‐Ichi Murahashi, Yoshiki Makabe,

Asymmetric Synthesis and Catalysis

Pd(0) complexes catalyze the 3-Aza-Cope rearrangement of N-allylenamines to the corresponding δ,ε-unsaturated imines or γ,δ-unsaturated carbonyl compounds in the presence of trifluoro-acetic acid as co-catalyst.