A Novel Platform for Modeling Oxidative Catalysis in Non‐Heme Iron Oxygenases with Unprecedented Efficiency
2008; Wiley; Volume: 14; Issue: 19 Linguagem: Inglês
10.1002/chem.200800724
ISSN1521-3765
AutoresAnna Company, Laura Gómez, Xavier Fontrodona, Xavi Ribas, Miguel Costas,
Tópico(s)Metalloenzymes and iron-sulfur proteins
ResumoBioinspired: A novel family of bioinspired non-heme iron complexes is described that catalyzes the H2O2 stereospecific alkane hydroxylation and olefin cis-dihydroxylation and epoxidation with unprecedented efficiency (K = ketone, A = alcohol, E = epoxide, D = diol, TN = turnover number). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2111/2008/z800724_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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