Artigo Revisado por pares

Sequential Staudinger/Pictet–Spengler cyclization strategy for the construction of tetrahydroisoquinolines of the bioxalomycin and ecteinascidin family of alkaloids

2001; Elsevier BV; Volume: 42; Issue: 4 Linguagem: Inglês

10.1016/s0040-4039(00)02015-3

ISSN

1873-3581

Autores

Brad Herberich, Masahiko Kinugawa, Alfredo Vázquez, Robert M. Williams,

Tópico(s)

Marine Sponges and Natural Products

Resumo

The use of the Staudinger ketene–imine β-lactam-forming cycloaddition reaction and the Pictet–Spengler cyclization reaction in sequence, has been used to prepare highly functionalized tetrahydroisoquinolines relevant to the bioxalomycin and ecteinascidin family of antitumor alkaloids.

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