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A New, High‐Yield Synthesis of Tetraphosphacubanes

1992; Wiley; Volume: 31; Issue: 6 Linguagem: Inglês

10.1002/anie.199207581

1521-3773

Thomas Wettling, Bernhard Geißler, R. Schneider, Stefan Barth, Paul Binger, Manfred Regitz,

Inorganic Chemistry and Materials

Angewandte Chemie International Edition in EnglishVolume 31, Issue 6 p. 758-759 Communication A New, High-Yield Synthesis of Tetraphosphacubanes†‡ Dr. Thomas Wettling, Dr. Thomas Wettling Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Bernhard Geissler, Dipl.-Chem. Bernhard Geissler Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorDr. Ronald Schneider, Dr. Ronald Schneider Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Stefan Barth, Dipl.-Chem. Stefan Barth Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Paul Binger, Prof. Dr. Paul Binger Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-W-4330 Mülheim an der Ruhr (FRG)Search for more papers by this authorProf. Dr. Manfred Regitz, Corresponding Author Prof. Dr. Manfred Regitz Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this author Dr. Thomas Wettling, Dr. Thomas Wettling Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Bernhard Geissler, Dipl.-Chem. Bernhard Geissler Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorDr. Ronald Schneider, Dr. Ronald Schneider Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Stefan Barth, Dipl.-Chem. Stefan Barth Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Paul Binger, Prof. Dr. Paul Binger Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-W-4330 Mülheim an der Ruhr (FRG)Search for more papers by this authorProf. Dr. Manfred Regitz, Corresponding Author Prof. Dr. Manfred Regitz Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-W-6750 Kaiserslautern (FRG)Search for more papers by this author First published: June 1992 https://doi.org/10.1002/anie.199207581Citations: 77 † Phosphorus compounds, Part 55. This work was supported by the Volks-wagen-Stiftung and the Fonds der Chemischen Industrie. Part 54: U. Bergsträsser, J. Hoffmann, M. Regitz, Tetrahedron Lett. 1992, 33, 1049-1052. ‡ Dedicated to Professor H.-G. Kuball on the occasion of his 60th birthday AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Cp2Zr complexes of type 1 of phosphaalkyne dimmers, readily available from [Cp2ZrCl2], RCP (R = t-Bu, CMe2Et, 1-adamantyl), and nBuLi, are the starting materials for the tetraphosphacubanes 2. When 1 is treated with hexachloroethane as a halogenating agent, its undergoes a novel dimerization with elimination of [Cp2ZrCl2] producing 2 in quite high yields (for R = tBu, 50% overall). Citing Literature Volume31, Issue6June 1992Pages 758-759 RelatedInformation