Structural Characterization of a Tris‐Agostic LanthanoidHSi Interaction
1996; Wiley; Volume: 35; Issue: 4 Linguagem: Inglês
10.1002/anie.199604191
ISSN1521-3773
AutoresWilliam S. Rees, Oliver Just, Herbert Schumann, Roman Weimann,
Tópico(s)Coordination Chemistry and Organometallics
ResumoAngewandte Chemie International Edition in EnglishVolume 35, Issue 4 p. 419-422 Communication Structural Characterization of a Tris-Agostic LanthanoidHSi Interaction†‡ Prof. Dr. William S. Rees Jr., Corresponding Author Prof. Dr. William S. Rees Jr. Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.edu William S. Rees, Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.edu Herbert Schumann, Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.deSearch for more papers by this authorDr. Oliver Just, Dr. Oliver Just Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.eduSearch for more papers by this authorProf. Dr. Herbert Schumann, Corresponding Author Prof. Dr. Herbert Schumann Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.de William S. Rees, Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.edu Herbert Schumann, Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.deSearch for more papers by this authorDr. Roman Weimann, Dr. Roman Weimann Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.deSearch for more papers by this author Prof. Dr. William S. Rees Jr., Corresponding Author Prof. Dr. William S. Rees Jr. Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.edu William S. Rees, Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.edu Herbert Schumann, Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.deSearch for more papers by this authorDr. Oliver Just, Dr. Oliver Just Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.eduSearch for more papers by this authorProf. Dr. Herbert Schumann, Corresponding Author Prof. Dr. Herbert Schumann Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.de William S. Rees, Georgia Institute of Technology, School of Chemistry and Biochemistry and School of Materials Science and Engineering and Molecular Design Institute, Atlanta, GA 30332-0400 (USA), Fax: Int. code +(404)894-1144, e-mail: will.rees@chemistry.gatech.edu Herbert Schumann, Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.deSearch for more papers by this authorDr. Roman Weimann, Dr. Roman Weimann Institut für Anorganische und Analytische Chemie, Technische Universität, Strasse des 17. Juni 135, D-10623 Berlin (Germany), Fax: Int. code +(30)314-22168, e-mail: schn0530@mailszrz.zrz.TU-Berlin.d400.deSearch for more papers by this author First published: March 1, 1996 https://doi.org/10.1002/anie.199604191Citations: 55 † This work was supported by the Deutsche Forschungsgemeinschaft and the U. S. Air Force Office of Scientific Research (Small Business Innovation Research contract from the Ballistic Missile Defense Organization to Spire Cooperation subcontract to Georgia Institute of Technology). ‡ Dedicated to Professor Herbert W. Roesky on the occasion of his 60th birthday AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract All the tert-butyl groups of [Er{N(tBu)[Si(CH3)2(H)]}3] (structure shown on the right) reside on the same face of the N3 plane, whereas all SiCH3 groups are rotated toward the periphery of the molecule. This results in ErH interatomic distances of 231.7–236.7 pm for the SiH moieties folded in toward the metal center. Citing Literature Volume35, Issue4March 1, 1996Pages 419-422 RelatedInformation
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