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Artigo Revisado por pares
BIBTEX RIS

2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

2013; Royal Society of Chemistry; Volume: 49; Issue: 86 Linguagem: Inglês

10.1039/c3cc46171h

ISSN

1364-548X

Autores

Hikaru Yanai, Yoichi Takahashi, Haruhiko Fukaya, Yasuo Dobashi, Takashi Matsumoto,

Tópico(s)

Organic and Inorganic Chemical Reactions

Resumo

Stable and easy-to-handle zwitterions containing carbanion and pyridinium moieties were synthesized, and their structural studies by both X-ray crystallography and theoretical methods revealed the stereoelectronic effect in the zwitterionic 'C−–C–N+' system.

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