Neutral complexes of gallium di-iodide containing Ga—Ga bonds
1991; Elsevier BV; Volume: 10; Issue: 1 Linguagem: Inglês
10.1016/s0277-5387(00)83553-6
ISSN1873-3719
AutoresJohn C. Beamish, Alan Boardman, I. J. Worrall,
Tópico(s)Ionic liquids properties and applications
ResumoThe complexes Ga2I4·2L (L = pyridine, 2-methylpyridine, 3-methylpyridine, 4- methylpyridine, morpholine, N-methylmorpholine, 1,4-dioxan, tetrahydrofuran, tetrahydropyran, dimethylsulphide, diethylsulphide, tetrahydrothiophene, 1,4-thioxan, 1,4-dithiane and tetramethylbiphosphine) have been prepared. Vibrational spectra indicate that the complexes adopt disubstituted ethane-like structures containing Ga—Ga bonds. We were unable to synthesize complexes of stoichiometry Ga2I4·4L which had previously been reported.
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