Triplet-mediated coupling of 5-bromo-1,3-dimetrhyluracil to Nb-methoxycarbonyltryptamine involving a double electron transfer
1979; Elsevier BV; Volume: 20; Issue: 42 Linguagem: Inglês
10.1016/s0040-4039(01)86505-9
ISSN1873-3581
AutoresSatoru Ito, Isao Saito, Teruo Matsuura,
Tópico(s)Chemical Synthesis and Analysis
ResumoOn acetone-sensitization, 5-bromo-1,3-dimethyluracil (1 reacts with Nb-methoxycarbonyltryptamine (4 under the assistance of an electron carrier such as 2-methoxynaphthalene to give a coupling product 6. A mechanism involving a double electron transfer via the triplet state of 1 is proposed.
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