Palladium‐Catalyzed Direct Arylation of Cyclic Enamides with Aryl Silanes by sp 2 CH Activation
2009; Wiley; Volume: 48; Issue: 29 Linguagem: Inglês
10.1002/anie.200901884
ISSN1521-3773
AutoresHai Zhou, Yun‐He Xu, Wan‐Jun Chung, Teck‐Peng Loh,
Tópico(s)Synthesis and Catalytic Reactions
ResumoIt does get in! A fluoride-assisted direct cross-coupling of cyclic enamides with trialkoxy aryl silanes by a palladium-catalyzed C--H activation leads to a wide range of enamides in yields of up to 95 %.
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