Artigo Revisado por pares

faceting induced by an ultrathin metal film: Pt on W(111)

1990; Elsevier BV; Volume: 227; Issue: 1-2 Linguagem: Inglês

10.1016/0039-6028(90)90376-j

ISSN

1879-2758

Autores

Ker-Jar Song, R. A. Demmin, Cheng-Zhi Dong, Eric Garfunkel, Theodore E. Madey,

Tópico(s)

Chemical and Physical Properties of Materials

Resumo

The interaction of ultrathin films on Pt with a W(111) surface has been studied using low energy electron diffraction (LEED), Auger electron spectroscopy (AES) and scanning tunneling microscopy (STM). When W(111) is covered with $̆1.1 × 1015 Pt atomscm2 and heated in the range 800–1600 K, the surface undergoes a massive restructuring to form microscopic facets. At 1200 K., the average facet dimensions are ≳ 100 Å, and the dominant facet orientation is W(211). The faceting appears to be driven by a Pt-enhanced anisotropy in the surface free energy.

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