The first asymmetric synthesis of chiral ruthenium tris(bipyridine) from racemic ruthenium bis(bipyridine) complexes
2000; Elsevier BV; Volume: 41; Issue: 15 Linguagem: Inglês
10.1016/s0040-4039(00)00230-6
ISSN1873-3581
AutoresDušan Hesek, Yoshihisa Inoue, Hitoshi Ishida, Simon R. L. Everitt, Michael G. B. Drew,
Tópico(s)Metal complexes synthesis and properties
ResumoThe first 'one-pot' asymmetric synthesis of ruthenium tris(bipyridine) derivatives starting from corresponding racemic ruthenium bis(bipyridine) complexes is described. This is achieved through the stereocontrolled formation of reactive intermediates derived from (R)-(+)- or (S)-(−)-methyl p-tolyl sulfoxide, which can be easily converted to the products with a retention of configuration at the metal center.
Referência(s)