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The first stable aldehyde and ketone complexes of zinc: the structure of [Zn(SeC 6 H 2 Bu t 3 ) 2 (p-OCHC 6 H 4 OMe)] 2

1991; Royal Society of Chemistry; Issue: 24 Linguagem: Inglês

10.1039/c39910001735

2050-5639

Manfred Bochmann, Kevin J. Webb, Michael B. Hursthouse, Muhammed A. Mazid,

Enzyme Structure and Function

The reaction of Zn(EC6H2But3)2(E = S or Se) with organic carbonyl compounds gives the first isolable aldehyde and ketone complexes of zinc as models for transient metal-substrate complexes in metalloenzymes such as liver alcohol dehydrogenase.