Mixed-metal complex [Fe(bipe)(Au(CN)2)2·MeOH] with gold clusters: a novel two-dimensional polyrotaxane net clipped by aurophilic interaction
2010; Royal Society of Chemistry; Volume: 12; Issue: 12 Linguagem: Inglês
10.1039/c0ce00376j
ISSN1466-8033
AutoresHaitao Xu, Gergely Juhász, Kazunari Yoshizawa, Masashi Takahashi, Shinji Kanegawa, Osamu Sato,
Tópico(s)Metal complexes synthesis and properties
ResumoA novel two-dimensional mixed-metal coordination polymer, [Fe(bipe)(Au(CN)2)2·MeOH], composed of polyrotaxane with Fe2(bipe)2 loops and rigid [Au(CN)2]− rods, forms a 2D → 2D parallel interpenetrating structure. The two networks are clipped by gold clusters via aurophilic interaction.
Referência(s)