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Nitrobenzene as a monodentate (O) and bidentate (O,O′) ligand: synthesis and structures of Zn(PhNO 2 ) n (OTeF 5 ) 2 (n= 2,3)

1990; Royal Society of Chemistry; Issue: 7 Linguagem: Inglês

10.1039/c39900000576

2050-5639

Paul K. Hurlburt, Patti J. Kellett, Oren P. Anderson, Steven H. Strauss,

Fluorine in Organic Chemistry

An X-ray crystallographic study of the first examples of complexes containing co-ordinated nitrobenzene, [Zn(PhNO2)2(OTeF5)2]2 and Zn(PhNO2)3(OTeF5)2, has proven that nitrobenzene can function as a bidentate (O,O′) ligand as well as a monodentate (O) ligand.