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Terminal Deoxy Hydroxyamino Sugars

1988; Taylor & Francis; Volume: 7; Issue: 1 Linguagem: Inglês

10.1080/07328308808058912

1532-2327

Jean M. J. Tronchet, Guido Zosimo‐Landolfo, N. Bizzozero, Daniel Cabrini, Ford Habashi, Evelyne Jean, Michel Geoffroy,

Magnetism in coordination complexes

Abstract Reduction of sugar aldoximes gave in good yield the corresponding terminal deoxy hydroxyamino sugars. These compounds were found to be reasonably stable (they could be kept for some weeks at 4° C). On standing in the air, these compounds in solution were spontaneously oxidized to the corresponding nitroxide free radicals whose ESR spectra gave useful structural information.