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Formation of a metallocyclophane via self-assembly of 2,3-bis(2,2′-bipyrid-6-yl)pyrazine and cobalt(II)

1997; Royal Society of Chemistry; Issue: 20 Linguagem: Inglês

10.1039/a705598f

2050-5671

F. Heirtzler, Thomas Weyhermüller,

Molecular Sensors and Ion Detection

Electrospray mass spectrometric, proton NMR, UV-titrametric, electrochemical and X-ray crystallographic studies have shown that, in the presence of cobalt(II), 2,3-bis(2,2′-bipyrid-6-yl)pyrazine self-assembles to form a dimeric metallocyclophane which is also stable in solution.