Packing of ions near an electrolyte-electrode interface in the HNC/LMSA approximation to the RPM model
1985; Elsevier BV; Volume: 117; Issue: 1 Linguagem: Inglês
10.1016/0009-2614(85)80402-4
ISSN1873-4448
Autores Tópico(s)Electrochemical Analysis and Applications
ResumoThe standard HNC/MSA calculation of the ion distribution fails to describe the packing in a second layer seen in MC calculations. We describe an improved treatment which employs the particle-particle direct correlation function for non-neutral electrolyte compositions as found near the surface.
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