Continuous Flow Determination of Carbon Dioxide in Water by Membrane Separation-Chemiluminescent Detection
1988; Taylor & Francis; Volume: 21; Issue: 10 Linguagem: Inglês
10.1080/00032718808066354
ISSN1532-236X
AutoresToyoaki Aoki, Imai Koichi, Makoto Munemori,
Tópico(s)Microfluidic and Capillary Electrophoresis Applications
ResumoAbstract Carbon dioxide has been found to enhance the chemiluminescence of a luminol system. A determination method for carbon dioxide in water was developed by applying this reaction to a continuous flow membrane-separation system. Concentrations of carbon dioxide as low as 0.04 μ g C /mL were determined. Membrane-separation effectively eliminates interferences from Co(II), Cr(III), Fe(III), and other ions which also enhance chemiluminescence. The relative standard deviation for this method was 2.8% (n=5) for 4.0 μ g C /mL and the time required for the analysis of one sample was 3.0 min.
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