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Industrial Oxidations with Organocatalyst TEMPO and Its Derivatives

2009; American Chemical Society; Volume: 14; Issue: 1 Linguagem: Inglês

10.1021/op900059x

1520-586X

Rosaria Ciriminna, Mario Pagliaro,

Chemical Synthesis and Reactions

The radical TEMPO and its derivatives find a variety of industrial applications as highly selective oxidation catalysts for the production of pharmaceuticals, flavors and fragrances, agrochemicals, and a variety of other specialty chemicals. Reviewing recent notable examples, we show how and why homogeneous and heterogeneous TEMPO-mediated oxidations are becoming part of a central toolbox in industrial organic synthesis applicable for the conversion of alcohols into aldehydes, ketones, and carboxylic acids.