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The Goldstone theorem and the Jahn-Teller effect

1967; IOP Publishing; Volume: 91; Issue: 1 Linguagem: Inglês

10.1088/0370-1328/91/1/331

1747-3810

J. Sarfatt, A. M. Stoneham,

Magnetism in coordination complexes

The Goldstone theorem requires that a many-body system with broken symmetry has an excitation branch, whose frequency tends to zero in the limit of infinite wavelength. We treat a system where the broken symmetry comes from the terms which give rise to the Jahn-Teller effect. Both the excitation branches we discuss in detail have finite frequencies at infinite wavelength when there is no Jahn-Teller term; the introduction of this term forces one branch to have zero frequency at infinite wavelength, in agreement with the Goldstone theorem The main point of this paper is this striking illustration of Goldstone's conjecture. Some of the simpler features of the excitation branches are discussed, they do not appear to have been treated in detail in the literature. Systems of ions in twofold degenerate E ground states may exhibit such excitations, which will have a characteristic velocity considerably less than that of sound.