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BIBTEX RIS

Stereospecific CH Oxidation with H 2 O 2 Catalyzed by a Chemically Robust Site‐Isolated Iron Catalyst

2009; Wiley; Volume: 48; Issue: 31 Linguagem: Inglês

10.1002/anie.200901865

ISSN

1521-3773

Autores

Laura Gómez, Isaac Garcia‐Bosch, Anna Company, J. Benet‐Buchholz, A. Polo, Xavier Sala, Xavi Ribas, Miguel Costas,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

Check for cavities: An exceptionally active nonheme iron catalyst employs H2O2 as an oxidant for the stereospecific hydroxylation of alkanes (see scheme). The iron site is located in a chemically robust cavity made up by the ligands.

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